The semiconductor industry uses chemical mechanical planarization cmp to planarize flatten and polish surfaces onto which circuitry will be deposited. Abrasive particle size plays a critical role in controlling the polishing rate and the surface roughness during chemical mechanical polishing cmp of interconnect materials during semiconductor processing. New book on modeling chemical mechanical planarization cmp integrated modeling of chemical mechanical planarization for submicron ic fabrication. Damascene process and chemical mechanical planarization. Chemical mechanical polishing systems ebara technologies. Pad conditioning effects in chemical mechanical polishing. Modelbased dummy feature placement for oxide chemicalmechanical polishing manufacturability ruiqi tian1 2,d. Copper surface chemistry relevant to chemical mechanical. The goal of chemical mechanical polishing cmp is to achieve a flat and smooth surface for through silicon via tsv application. Cmp chemical mechanical planarization cabot microelectronics. Discover cabot microelectronics cabot microelectronics corporation, headquartered in aurora, illinois, is the worlds leading supplier of chemical mechanical planarization cmp polishing slurries used in semiconductor manufacturing, and second largest cmp pads supplier to the semiconductor industry.
Chemical mechanical polishing cmp head table rotation head rotation oscillation down force slurry conditioner table pad backing film retainer ring wafer x y z cmp was first introduced to semiconductor process to planarize ild. In chemical mechanical polishing cmp, even the soft pad asperities may, under certain conditions, generate scratches on the relatively hard surfaces being polished. In this study, cmp performance of three electronic materials was investigated. For the kinetics of the chemical mechanical polishing cmp of wafers containing periodic metaldielectric structures, a model is developed and theoretically investigated with the use of contact. The present invention has particular applicability to doublegate devices. In principle, cmp is a process of smoothing and planing surfaces with the combination of chemical and mechanical forces. Back to top product overview rohm and haas electronic materials cmp, inc. Cmp is a standard manufacturing process practiced at the semiconductor industry. Diamond structuredependent pad and wafer polishing performance.
Chemical mechanical polishing of hard disk drive substrates shyam s. Snider department of electrical engineering, university of notre dame, notre dame, indiana 46556. Pad conditioning effects in chemical mechanical polishing a. An efficient and high quality chemical mechanical polishing. Material removal mechanism in chemical mechanical polishing. A technique for measuring slurryflow dynamics during chemicalmechanical polishing j. Available formats pdf please select a format to send. Cr1, cr6, cr10, cr15, cr30f, cr125, cra6 are jetmill deagglomerated powders. Chemical mechanical polishing cmp is a promising means of technique for removing excess copper and planarizing the surface on a global scale. The planarization technology of chemical mechanical polishing cmp, used for the manufacturing of multilevel metal interconnects for highdensity integrated circuits ic, is also readily adaptable as an enabling technology in micro electro mechanical systems mems fabrication, particularly polysilicon surface micromachining. Overview generalized schematics of cmp and postcmp clean current cmp environment evolution of cmp the cmp module the cmp infrastructure section b.
In the present study, contact mechanics models of padinduced scratching are. Wong1, robert boone2 1department of computer sciences, university of texas at austin, austin, tx 78712 2motorola inc. Chemical mechanical polishing cmp has emerged as an enabling technology for manufacturing multilevel metal interconnects used in highdensity integrated circuits ic. Pdf abrasive for chemical mechanical polishing researchgate. In general, higher chemically active slurries will have a higher amount of recess due to the wet etching action of the slurry. Based on this force field, we used molecular dynamics simulations to illustrate the chemistry at the cusilica abrasive interface and cu atom. Dual silicon layer for chemical mechanical polishing. The chemical mechanical polishing cmp process has emerged as a critical technique to smooth surface topography. Venkataraman laboratory for advanced surface planarization lasp clarkson university presented at fifth annual levitronix cmp users conference february 10, 2009 santa clara, ca. Post cleaning chemical of tungsten chemical mechanical. Modelbased dummy feature placement for oxide chemical. Stewart final seminar august, 2008 cu has replaced aluminum for interconnects in microelectronic devices because it possesses.
To clarify the chemical mechanical polishing cmp mechanism of cu in aqueous hydrogen peroxide and glycine, we developed a reaxff reactive force field to describe the interaction between cu, slurry h2o, h2o2, and glycine, and the silica abrasive. Chemical mechanical polishing cmp is often associated with chemical mechanical planarization which is a polishing process assisted by chemical reactions to remove surface materials. In order to enable highk metal gate technology, new chemical mechanical planarization steps or slurries are needed to meet the stringent planarity or defect requirements for device performance. Chemical mechanical polishing cmp cnf users cornell.
The use of the cmp always includes these 5 following steps. Chemical mechanical polishing of silicon carbide the high temperature integrated electronics and sensors hties team at the nasa lewis research center is developing silicon carbide sic as an enabling electronic technology for many aerospace applications. The size of the abrasive particles plays a critical role in controlling the polishing rate and the surface roughness during chemical mechanical polishing of interconnect materials during. Scott lawing rohm and haas electronic materials cmp technologies. Cmp chemical mechanical polishing steag mecapol 460. Chemical mechanical planarization slurry distribution system. Pdf on oct 24, 2018, hong jin kim and others published abrasive for chemical mechanical polishing find, read and cite all the research. Diamond polishing powder ideal for polishing small rock speciments, minerals, thin sections and metallic ores, where special lubricant carriers are requried. Pdf chemical mechanical glass polishing with cerium oxide. One application in which planarization is essential is the manufacture of computer chips. Analysis of sapphire chemical mechanical polishing using.
Dornfeld abstract the abrasion mechanism in solidsolid contact mode of thechemical mechanical polishingcmp processis investigated in detail. In oxide chemical mechanical polishing cmp, excellent planarization i. Mechanics of the padabrasivewafer contact in chemical. Ild, imd cmp sti cmp w, cu cmp buffing cmp with improvements in equipment and consumables, cmp is used in sti cmp. Chemical mechanical polishing or planarization is a process of smoothing surfaces with the combination of chemical and mechanical forces. In our previous study we clarified that the linear velocity ratio, defined as the ratio of slurry flow velocity to pad linear velocity, remarkably affected the stability of the removal rate. Introducing chemical mechanical polishing in the wafer bonding will make a large range of. Chemical mechanical polishing cmp is a process that is used to remove surface irregularities and to obtain uniform planarization of a silicon wafer surface. In this work we present extension of cmp from submicron ic manufacturing to fabrication of complex surfacemicromachined microelectromechanical systems mems. Lynn fuller, professor cmp page 2 rochester institute of technology microelectronic engineering cmp chemical mechanical planarization.
In chemical mechanical polishing, a substrate is planarized with one or more fixedabrasive polishing pads. The machine is based on the popular kemet 15 lapping and polishing machine, but incorporates stainless steel elements in place of painted components for longer life, and contamination free polishing. Chemical mechanical polishing with multiple polishing pads. Apr 19, 2016 we applied our original chemical mechanical polishing cmp simulator based on the tightbinding quantum chemical molecular dynamics tbqcmd method to clarify the atomistic mechanism of cmp processes on a cu111 surface polished with a sio2 abrasive grain in aqueous h2o2. Controlled chemical mechanical polishing of polysilicon and. Cmp not only eases the design and manufacturability of mems. The user should be aware that the nature of the chemical polishing process demands care and personal protection at all times. Chemical mechanical planarization for microelectronics applications. Using special barrier layers to stop copper diffusion. Chemical mechanical polishingplanarization typical process conditions pressure. Chemicalmechanical polishing behavior of tantalum in. Division of engineering and applied sciences, harvard university, 29 oxford street, cambridge, ma 028, usa received 27 may 2003. A contactmechanics based model for dishing and erosion in chemicalmechanical polishing joost j.
Modeling planarization in chemicalmechanical polishing. The goal of the 1st phase cmp is to remove copper layer with high efficiency. Characterization and modeling of oxide chemicalmechanical. Background art the escalating demands for high density and performance. This is the process where the top surface of a wafer is polished with a slurry containing an abrasive grit, suspended within reactive chemical agents. At one time, the cmp process was viewed as too dirty to use for the highlyprecise business of semiconductor manufacturing. Investigation of chemicalmechanical polishing of niobium. Cmp since that was the purpose for which it was created. Chemical mechanical planarization is a polishing process, wherein, the chemical slurry and mechanical polishing processes are used to remove unwanted conductive or dielectric materials on the silicon wafer.
Pdf pad scratching in chemicalmechanical polishing. A model for chemicalmechanical polishing of a material surface based on contact mechanics j. Pdf chemical mechanical polishing of cubic silicon. Ebaras applications engineering groups in japan and the u. Cmp is a method through synergistic effects of chemical and mechanical forces to achieve local and.
The cmp process combines the chemical acidic or basic effect of the slurry, which contains microabrasives with the mechanical effect provided by polishing to reduce topography on the wafer surface. Chemical mechanical polishing cmp technology has successfully met the stringent requirements of ultraplanarized surfaces in semiconductor manufacture. Apr 27, 1999 chemical mechanical polishing the layer with a fixedabrasive polishing pad until a residual layer remains over the surface, the residual layer having a thickness equal to or greater than the depth of any scratches therein. Chemical mechanical glass polishing with cerium oxide. When the machine boots up, the software looks for a configuration file in the same folder as the cmp. Recycling a slurry for reuse in chemical mechanical planarization of. Microscratch induced by chemical mechanical polishing cmp is a chronic problem to device yieldkilling and its criticality becomes more important in sub14nm device manufacturing. Then the substrate is polished with a standard polishing pad to remove scratch defects created by the fixedabrasive polishing pads. A model for chemicalmechanical polishing of a material. Present and future role of chemical mechanical polishing in wafer. Ultrarapid polishing of silicon carbide sic substrates. Earlier reports on the effect of particle size on polishing of. Chemical mechanical polishing cmp is the planarization method that has. Theory and experiment for several decades, chemical mechanical polishing cmp has been.
Chemical mechanical polishing system operation manual. Chemical mechanical planarization pt 01003jt 4 a 2phase process is adopted in our inlaid copper pattern wafer polishing, which means changing slurry and working conditions during the copper removal process. Aluminum is proposed for the mems structure because it can be deposited at relatively low temperatures below the cmos degradation temperature of 450 c. Chemical mechanical planarization cabot microelectronics. By controlling the pore size, porosity, and pad hardness one is able to manufacture cmp polishing pads that offer tunable pad properties. Gutmann, chemical mechanical planarization of microelectronic materials, wiley and sons, new york 1997. Chemical mechanical planarization solutions chemical mechanical planarization cmp is a polishing process, which utilizes a chemical slurry formulation and mechanical polishing process to remove unwanted conductive or dielectric materials on the silicon wafer, achieving a nearperfect flat and smooth surface upon which layers of integrated circuitry are built. Chemical mechanical polishing of cubic silicon carbide films grown on si100 wafers. To do this, chipmakers use a process called chemicalmechanical planarization, or cmp, for short. Chapter 12 chemical mechanical polishing hong xiao, ph. Pad height pdf asperity aspect ratio dh30 20 10 0 10 f r equenc y. Dual silicon layer for chemical mechanical polishing planarization technical field the present invention relates to semiconductor devices and methods of manufacturing semiconductor devices. Mechanical grinding alone may theoretically achieve planarization but the surface damage is.
Additionally, new materials such as cu and w, introduced in ulsi fabrication, also require extensive use of the cmp process to form inlaid interconnect structures. Chemicalmechanical polishing cmp processes produce both global and local planarization through relatively simple and quick processing. Chemical mechanical planarization cmp polishing pads. Barrier layers prevent the intermixing of materials above and below the barrier. For several decades, chemical mechanical polishing cmp has been the most widely used planarization method in integrated circuits manufacturing. The final polishing results are affected by many factors related to the carrier structure, the polishing pad, the slurry, and the process parameters.
The customer must ensure that any extraction system used is suitable for use with the cmp. Controlled chemical mechanical polishing of polysilicon and silicon dioxide for singleelectron device vishwanath joshi,a alexei o. We reveal that the oxidation of the cu111 surface mechanically induced at the friction interface is a key process in. It can be thought of as a hybrid of chemical etching and free abrasive polishing. A technique for measuring slurryflow dynamics during chemical mechanical polishing j. A technique for measuring slurryflow dynamics during. Chemical vapor deposited cvd diamond films, as a first materials, was fabricated. Application of chemicalmechanical polishing to planarization. Chemical mechanical polishing cmp is a process that is used. Chemical mechanical polishing cmp ara philipossian intel corporation 1999 arizona board of regents for the university of arizona outline of the tutorial section a.
Effect of polishing pad material properties on chemical. Us5897426a chemical mechanical polishing with multiple. What is chemical mechanical polishing or cmp polishing. Media in category chemicalmechanical polishing the following 5 files are in this category, out of 5 total. Typical barrier materials are ta,tan, tin, and tiw. Copper surface chemistry relevant to chemical mechanical planarization cmp karen l. This process uses a tool with a rotating wafer carrier single or multihead and a polishing pad placed on a rotating platen. Pad conditioning is the process of dressing the polishing pad pad is contacted with an abrasive medium, typically a diamond abrasive.
Controlled chemical mechanical polishing of polysilicon. This analytical solution is compared with experimental data from journal of electronic materials, 25, no. Chemical mechanical polishing cmp processes produce both global and local planarization through relatively simple and quick processing. Oxide cmp 2800amin metal cmp 3500amin cmp is a process of smoothing surfaces with the combination of chemical. The model results agree with the experimental removalrate decay results. Atomic bonds are weakened or broken, and removal is based on chemical reactions between the slurry and the surface and the mechanical effect of the abrasive particles. Chemical mechanical planarization of electronic materials.
Dishing occurs when the polishing pad under the pressure of polishing, is able to. During planarization, a wafer held upside down by a rotating wafer carrier is. B s pabla3 1 research scholar, mechanical department,national institute of technical teachers training research chandigarh india. Chemical mechanical polishing is more commonly known as cmp polishing. Much effort has been devoted to the study of cu cmp with some different mechanisms proposed 14. Atomistic insights into cu chemical mechanical polishing. Mechanics of the padabrasivewafer contact in chemical mechanical polishing a dissertation presented by dincer bozkaya to the department of mechanical and industrial engineering in partial fulfillment of the requirements for the degree of doctor of philosophy in mechanical engineering northeastern university boston, massachusetts may, 2009. Solid state microcellular foaming ssmf process was used to produce porous cmp pads in a variety of pore size and porosity range, using a variety of tpu resin hardness.
Cmp chemical mechanical polishing steag mecapol 460 user. The kemcol 15 machine is ideal for chemical mechanical polishing cmp, and cerium oxide based polishing applications. This planarization technique alleviates processing problems. A production chemical mechanical planarization cmp tool in a. Commonly, polyurethane based pads have been used to achieve this level of planarization.
This phase stops at the surface of the barrier layer. Hardness compressibility corrosion resistance use of chemicals to remove adhesive residues mechanical padpullers are becoming a requirement in factories polishing pad life frequency of changing pads as a function of pad life. The mechanism is different from grinding, as chemical mechanical polishing cmp works in the atomic regime. Uses chemical mechanical planarization cmp instead of etching. Whether this entails planarizing exotic new materials or providing proven solutions for todays copper, oxide, tungsten, or sti challenges across an array of technology.
Cmp involves pouring a mixture of chemicals and sand moreorless on a spinning disc of special sandpaper and polishing away. Atomistic mechanisms of chemical mechanical polishing of a cu. Chemical mechanical polishing of hard disk drive substrates. Cmp polishing pads are designed for polishing and finishing a wide variety of surfaces where flatness and ultraprecision surface finish is critical. This document is intended to introduce the techniques of chemical mechanical polishing cmp to the new user so that they may be better prepared to integrate cmp into their process flow. Figure 1 illustrates the cmp process in which an oxide surface is planarized by rotating a wafer under pressure against a polishing pad in the presence of a silicabased alkaline slurry. Chemical mechanical planarization of electronic materials by fnu atiquzzaman a thesis submitted in partial fulfillment of the requirements for the degree of master of science department of mechanical engineering college of engineering university of south florida comajor professor. Colloidal aspects of chemical mechanical polishing cmp. It can, in a way, be thought of as a hybrid of chemical etching and free abrasive polishing. Effect of selected physicochemical characteristics on polishing efficiency article pdf available june 2016 with 2,151 reads how we. Vlassak division of engineering and applied sciences, harvard university 311 pierce hall, 29 oxford street, cambridge ma 028 abstract we present a new model for dishing and erosion during chemical mechanical planarization. Analytical solution for polishrate decay in chemical.
Large or infrequently accessed files can take several minutes to retrieve from our archival storage system. The polishing action is partly mechanical and partly chemical. Logitech chemcloth polishing cloths are designed to meet the needs of todays chemical mechanical polishing cmp operations. Cmos chip planarization by chemical mechanical polishing for a vertically stacked metal mems integration figure 1. Cmp chemical mechanical planarization solutions for the integration of highk metal gate technologies. Chemical mechanical polishing machine cmp the kemcol 15 machine is ideal for chemical mechanical polishing cmp, and cerium oxide based polishing applications.
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